Which muscle is this and how to build it?

In a lot of. Arnold Schwarzenegger bodybuilding pics, especially the side chest ones, there is a muscle jutting out of back.

I have posted a pic here. https://www.tumblr.com/aks2161989/774077064229912576/which-muscle-is-the-circled-part

Check out the circled part

What muscle is this? Which exercises should you do to build this muscle?